A Dictionary of Applied Chemistry volume 1

Cover A Dictionary of Applied Chemistry volume 1
A Dictionary of Applied Chemistry volume 1
Thomas Edward Thorpe
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This oxychloride is readily decomposed by water or alcohol.
Barium chlorate Ba(C10 3 ) 2 . Dry Ba(OH) 2 does not absorb chlorine, but. In presence of water it rapidly takes it up, forming first hypo- chlorite and chloride, the former of which breaks up into chlorate and chloride 6BaO-f6Cl 2 -=5Baa 2 +Ba(C10 3 ) 2 (Konigel-Weisberg, Ber. 12, 346).
As ic is difficult to separate from the chloride, the chlorate is best prepared by neutralising a solution of chloric acid with barium carbonate and e
...vaporating to the crystallising point. It crystallises in colourless monoclinic prisms with 1 molecule of water, soluble in 4 parts of cold and less than 1 part of boiling water.
Barium chlorate is also slightly soluble in alcohol, and the alcoholic solution burns with a green flame.
If strongly heated fused barium chlorate be plunged into a jar of coal gas, a brilliant com- bustion of the carbon and hydrogen contained in the coal gas occurs at the expense of the oxygen of the chlorate.
Barium perehlorate Ba(C10 4 ) 2, 4H, 0 is readily formed by neutra Using perchloric" acid with barium hydrate or carbonate.


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