A Handbook of Colloid-Chemistry: the Recognition of Colloids, the Theory of ...
A Handbook of Colloid-Chemistry: the Recognition of Colloids, the Theory of ...
Carl Wilhelm Wolfgang Ostwald
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Gatin-Gruszewska (I.e.) finds highly purified glycogen to have a "molecular weight" of 140,000 or more. Of measurements of the boiling point of colloid systems those of F. Krafft and his pupils (I.e.) deserve special mention. The following table shows a particularly interesting series of their experiments. It shows at the same time that in the lower mem- bers of a homologous series the observed molecular weights in aqueous solution are at first lower than calculated, while the 1 See in this con...nection the textbooks of physical chemistry; for example, Wiih. Ostwald, Grundr. d. allg. Chem. 4 Aufl., 341, 375, etc., Leipzig, 1909. • For literature see p. 129. Digitized by LjOOQIC MECHANICAL PROPERTIES OF COLLOID SYSTEMS 143 reverse is true with the higher members. We deal, in other words, with a series of dispersoids which vary in the degrees of their dispersion. Dispersion values characteristic of colloids begin, approximately, with nonylate. Table ii. — Molecular Weights of Aqueous Sodium-soap Solutions (Determined by Boiling-point Measurements.
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