A Laboratory Manual, Containing Directions for a Course of Experiements in Organic Chemistry, Systematically Arranged to Accompany Remsen's Organic Chemistry

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Does NHiBr forin a perbromide?
(a) Heat some of the dry salt cautiously on platinum foil, and note what takes place. Does the salt explode on percussion? Try it (&) Boil some with absolute alcohol, and describe what takes place. What are the products of the reaction?
(c) Boil a little of the dry salt with water. What takes place? What are the products of the reaction?
Prove it.
(d) Treat a cold solution of dimethylaniline in water with a cold aqueous solution of benzene diazonium chlo- ride and
... observe what takes place. Explain.
(e) Treat a cold solution of phenol in water with a cold aqueous solution of benzene diazonium chloride and make the solution alkaline with sodium carbonate solution and note what takes place. Explain.
110 EXPERIMENT 54 lODOBENZENE, lODOBENZENE DICHLORIDE, AND lODOSOBENZENE Dissolve JO grams of freshly distilled aniline in a mix- ture of 50 grams cone, hydrochloric acid and 150 cc. of water in a 500 cc. Erlenmeyer flask. Cool the mixture with ice wa,ter below 8° and add gradually, with constant shaking, a cold solution of 9 grams of sodium nitrite in 50 cc.


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