A Manual of Blow-Pipe-Analysis. And Determinative Mineralogy

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A Manual of Blow-Pipe-Analysis. And Determinative Mineralogy
William Elderhorst
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The presence of antimony is ascertained as shown 49. Zinc, 113. Iron, 83.
It dissolves with some difficulty in boiling hydrochloric acid, with evolution of sulphuretted hydrogen. Very dilute nitric acid has no effect on it, but by a stronger acid it is readily dissolved with evolution of nitrous acid vapors. By fuming nitric acid and aqua regia it is very violently acted upon, being converted into sulphate, or a mixture of the sulphate with the chloride.
Bournonite.
170. 3Cu 2 S, SbS 3 +2(3PbS,
... SbS 3 ). 11^2. 53. G= 5. 7 5. 9. Occurs crystallized, and massive, granular, compact; lustre metallic; color and streak steel-gray.
In a matrass, decrepitates and yields with a strong heat a dark- red sublimate. In an open tube, sulphurous acid is evolved and abundant antimonial fumes, which condense partly on the upper and partly on the lower side of the tube; the former consist of anti- monious acid, which is volatile; the latter is not volatile, and con sists of a mixture of antimonate of oxide of antimony with afitimo- nate of lead.


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