A Practical Course in Qualitative Analysis, for Use in High Schools And Colleges

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(AgCl), insoluble in HNO3, soluble in H4NHO, turns violet in sunlight. (Usually boil the solution in HNOg.) 2. Add H2SO4 and MnOg, and heat. Clj fumes appear, which bleach moist litmus paper.
3. Add Hgj(N03)2, mercurous nitrate, white pp.
(HgCl); pp. is insoluble in HNO3, but is blackened by H4NHO.
Chloric (HOlOs)- Add strong HgSO^, yellowish gas (CI3O4) is liberated with explosive violence. Use a small quantity and without applying heat.
Note. — Deflagration is always an indication of nitrates
... or chlorates.
Carbonic (HgOO,) and the Carbonates.
1 . Add HCl or HNO3, effervescence, tested by passing gas through lime water (Ca2H0), white pp. (CaCOj).
68 QUALITATIVE AKALYSIS.
2. Gas set free in 1 is odorless, and will extinguish a lighted match.
Hydrobromio iHBr).
1 . Add AgNOj, yellowish- white pp. ( AgBr), insoluble in HNO3; slightly soluble in H4NHO, easily soluble in KCy.
2. Add H2SO4 and MnOj, and heat; brown vapors of Brg appear.
3. Add chlorine water, then a few drops of CSg; shake, and CSj will be colored brownish-yellow.


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