A Short Course in Quantitative Chemical Analysis

Cover A Short Course in Quantitative Chemical Analysis
A Short Course in Quantitative Chemical Analysis
Appleton, John Howard, 1844-1930
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Ttie Value of the Stannous Solution.
Take 20 cubic centimetres of the standard Ferric solu- tion (prepared as above, page 123) ; place them in a casse- role with 20 cubic centimetres of pure concentrated hy- drochloric acid, and boil ; while the solution is boiling,® run in, from a burette, the Stannous chloride solution until the yellow color of the Iron solution is wholly destroyed.
Fe, (SO^), + Sn CI, + 2 H CI = 2 Fe SO4 -|- Sn Cl^ + H, SO4.
Place the casserole, with its contents, in a basin
... of cold water to cool. When cold,^ add 5 cubic centimetres of the Starch paste, and run in the Iodine solution until the blue color is produced.
Knowing the value of the Iodine solution in terms of the Tin solution, the exact number of cubic centimetres of the Tin solution required for 20 cubic centimetres of the Ferric solution may be calculated.
Repeat the operation with three different portions, of 20 cubic centimetres each, of the Ferric solution.
From the average number of cubic centimetres of the Tin solution used find the value of one cubic centimetre of the Tin solution in terms of Iron solution, and from that, by calculation, its value in terms of metallic Iron.


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