A Study of Adsorption Phenomena in the Vicinity of the Critical Temperature
A Study of Adsorption Phenomena in the Vicinity of the Critical Temperature
Walter Creigh Preston
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io of H2O in the Gel Z/M 0. 03 40. 5 0. 77 41. £ 1. 96 43. 0 3. 57 41. 0 3. 77 40. 0 Long points out that, of the gels he used, the sample containing 1. 965^^ of HgO seems to possess the maximujn activity and capacity; that increasing the water content brings about both a decrease in activity and in capacity of the gel, while a decrease in water content to C. 77% apparently affects only tiie capacity. Anhydrous gel shov/s a slight decrease in both properties, but in eae4^ case t]ie change is so... snail as to in- dicate only minor structural changes, and not complete de- struction as was formerly thought. That the adsorption is strictly reversible was proven by lIcGavacIc, who showed that the hysteresis noted bj* earlier worhers was fallacious; that identical results can be obtained 1. LIcGavach & Patricl:- Log. Cit. upon rilling and emptying the pores provided the gel has "been previously completely freed from adsorbed air and other per- manent gases. Tailxire to v/orl: with air-free gel, varying the water content, and the use of non-homogeneotis gel samples prob- ably account for many previously noted anomalies in the behav- ior of the gel.
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