A Study of the Absorption Spectra of Solutions of Certain Salts of Potassium Co
A Study of the Absorption Spectra of Solutions of Certain Salts of Potassium Co
Harry Clary Jones
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Of a 3. 04 normal aqueous solution of aluminium chlo- ride and to this were added 2 c. C. Of hydrochloric acid and zinc, so that the uranyl salt was reduced to the uranous condition. To a 2 mm. Depth of solution was added water so as to make the depth of cell 7 mm. The addi- tion of water caused the 6, c, d, and e bands to become very faint and to be shifted to the violet. The band at A 4980 and especially the bands at >l 5500, A 6500, and A 6750 were very considerably shifted. The solution of ...7 mm. Thickness showed bands at M 4130, 4210 (narrow), 4285, 4420(7). URANOTJS CHLORIDE IN HYDROCHLORIC ACID AND ACETONE. A 0. 2 normal solution of uranyl chloride in strong hydrochloric acid was reduced by using as little zinc as possible. Plate 70, A, shows the absorption spectra of this solution to which acetone has been added. Strip 1 repre- sents the absorption of 5 mm. Of the hydrochloric acid solution; strip 2 the same to which 1 mm. Of acetone has been added; strip 3, 3. 3 mm. Acetone, and strip 4, 12 mm.
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