A Study of the Factors Influencing the Anodic Passivity of Iron With Notes On Po
A Study of the Factors Influencing the Anodic Passivity of Iron With Notes On Po
Seth Chapin Langdon
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768 23 1. 730 25 1. 748 26 1. 760 27 1. 770 28 1. 760 30 1. 751 31 1. 740 32 1. 730 34 ' 1. 767 35 +0. 520 38 + 0. 520 40 1. 775 41 1. 776 44 1. 728 48 1. 747 50 1. 755 51 1. 761 53 1. 770 Iron active and no external current Iron rendered passive then current lowered to 10 M. A. Lowered to 10 M. A. Oxygen pressure turned on 43. 9 Ibs. Oxygen pressure off Oxygen pressure 18. 7 Ibs. 43. 9 " 43. 9 " 43. 9 " No pressure Oxygen pressure 43. 9 Ibs. 30. 5 " 25. 8 " No pressure Oxygen pressure 25. 8 Ib...s. 30. 5 " 34. 6 " 43. 9 " No pressure External 10 M. A. Current stopped Iron active Iron rendered passive and current lowered to 10 M. A. Hydrogen pressure 43. 9 Ibs. 34 30. 5 " 25. 8 " No pressure fact that the change of potential was coincident with the application of the pressure and independent of the gas led to the suspicion that perhaps the phenomena was not characteristic of passive iron alone. To test this potential determinations were made, under analagous con- ditions, on the following electrodes; an iron cathode, platinum anode and cathode, and a copper anode Table XIII shows the changes pro- duced.
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