A Study of the Solubilities of Liquids in Liquids the Partition of the Lower Al
A Study of the Solubilities of Liquids in Liquids the Partition of the Lower Al
Benjamin Blackiston Wroth
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3 6. 41 1. 70 047 5. 32 2. 53 1. 30 0. 68 t 5' 012345 Number of Carbon Atoms in AJcoho/s. 17 18 The ratios decrease rapidly as the number of carbon atoms in the alcohol increase, each ratio being approxi- mately one-fourth of the preceding ratio. Taking these ratios as fractions, the numerators which represent the solubilities of the alcohols in water, in- crease as number of carbon atoms decrease, while the de- nominators, or the solubilities of the alcohols in the oil increase in the opposite... directions. For this reason the square roots of these ratios have been plotted against number of carbon atoms in the curve. (See page 17). The solubility of methyl alcohol in cottonsed oil appears to be 4. 84 g. Per 100 cc. While for ethyl alcohol it is 21. 2 or about four times as great. We have 4. 84 x 103. 6 = 505 and 21. 2 X 28. 3 = 600. From this 505 g. Methyl alcohol and 600 g. Ethyl alcohol should dissolve in 100 cc. Water. These represent, in the same approximation, what may be termed ideal solubilities.
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