A System of Physical Chemistry, volume 3

Cover A System of Physical Chemistry, volume 3
A System of Physical Chemistry, volume 3
William Cudmore Mccullagh Lewis, James Rice
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As regards the process of absorption of radiation, the ekistence of Kirchhoff^s law {viz. that a body absorbs radiation of the same wave- length as it emits), naturally suggests that the same mechanism is to be attributed to absorption as to emission, absorption taking place when an electron passes from an inner orbit to an outer.
Bohr's theory is likewise in agreement with Einstein's expression for the photo-electric effect, viz, T -= ^v - W, where T is the kinetic energy of the electron eject
...ed under the influence of light of frequency V, and W is the total amount of energy which would be emitted during the act of binding a free electron to the nucleus of the atom {cf^ following chapter).
We have now to consider in more detail what has been called the permanent state of an atomic system. We have seen that in the case of a system consisting of a nucleus and a single electron, the permanent state is defined by the condition that the angular momentum of the electron is hliir. The atom of hydrogen corresponds to this system, but the atom of hydrogen is difficult to deal with because of the very slight dissociation of gaseous molecular hydrogen.


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