A Text book of Inorganic Chemistry

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This operation is continued until a definite proportion ((either two-thirds or "seven-eighths, depending upon the propor- tion of silver) has been removed. The residue is then transferred to the neighbouring pot on the opposite side, and a second charge melted up in the first pot. As the neighbouring pots fill up, they are similarly treated, and in this way an alloy, gradually becoming richer and richer in silver, is passed along in one direction, and purer and purer lead is sent in the opposit...e way. The rich alloy is then cupelled.
The Parkers process depends upon the fact that when zinc is added to a melted alloy bf lead and silver, the zinc deprives the lead of the silver, and itself forms an alloy with it. The alloy of zinc and silver rises to the surface, and is the first portion to solidify, and can be removed. The operation is carried out in iron pots.
The argentiferous lead is melted, and a quantity of zinc is thoroughly stirred into the molten mass, the amount of zinc depending upon the richness of the lead.


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