A Text book of Organic Chemistry

Cover A Text book of Organic Chemistry
A Text book of Organic Chemistry
A F Arnold Frederik Holleman
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The researches of recent years have, however, shown that essential differences do not really exist. To begin with, we have come upon many cases of transition between colloidal and real solutions. Furthermore, it was previously observed by LOBRY DE BRUYN that salt solu- tions can be separated by centrifugal force into portions of unlike concentration. More important still, the investigations of EINSTEIN, PERRIN, SVEDBERG and others have shown that colloids, just like true solutions, are subject ...to the osmotic laws.
197. ] GERMANIUM. 273 From the molecular-kinetic point of view there is no difference, according to these investigations, between a " dissolved molecule ' and a " suspended particle"; consequently a mechanical sus- pension must exert exactly the same osmotic pressure as a " true solution " of the same number of particles per unit volume. The fact that the colloidal solutions display no properties cor- responding to osmotic pressure is simply due to the fact that at the same concentration the number of freely moving particles in solutions is enormously greater than with the colloids, i.


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