A Text-Book of Physics : With Sections On the Application of Physics to Physiology And Medicine

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The steam can obviously not be varied in composition, but it may be varied in pressure while the temperature is kept constant (provided we do not increase its pressure so far. as to make it condense), and it may be varied in temperature while .kept under constant pressure (with the same proviso as to condensation brought about by cooling). There are, consequently, two independent variations possible without passing out of the given phase, or, as it is -stated, two degrees of freedom. We have he
...re left out of account a mere change in the quantity of steam, apart from any change in its condition, for, as we shall see throughout, the quantity of any phase present is without influence on the state of equilibrium reached (in marked contrast to the effect of the quantity of the different constituents within one phase, as considered in the preceding section). But suppose that the steam is brought into a state in which some of it condenses to water : there are then two phases. We have seen already (p.

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