Alternative Decouplings of the Electron Propagator
Alternative Decouplings of the Electron Propagator
Born, Gregory Jay
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2 b 4a j 23.39 21.75 23.30 21.79 21.15 b 5aj 17.29 14.99 17.38 15.33 16. 2 C lb. 14.56 14.11 14.45 14.03 14.5 C ' d lb 2 19.47 17.91 19.08 17.77 17. C 2b 12.06 9.92 11.93 10.11 10. 9 C a Jolly and Schaaf (1976). b Hood et aj_. (1976). Estimated center of gravity (Cederbaum and Domcke, 1977) from spectrum of Turner et a]_. (1970). d 14.38(8) VIP (Turner et al., 1970). 107 interact, level shifts and intensity changes are observed. In these regions, even the nondiagonal 2p-h TDA is not fully satis...factory since ion-state relaxation and hole-hole interactions, neither of which are described by this self-energy approximation, may also be important (Wendin, 1979). CHAPTER 5 PHOTOIONIZATION INTENSITIES 5.1 Introduction The evaluation of each decoupling approximation in the preceding chapters was based on the comparison of propagator poles to experimental ionization energies. This criterion represents a particular bias since it does not reflect the quality of the Feynman-Dyson amplitudes (defined in Section 1.1).
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