An Advanced Course in Quantitative Analysis

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58 QUANTITATIVE ANALYSIS slightly exceeded. Add to the filtrate 10 cc. Of magnesia mixture and shake. Place the flask in ice water and allow to stand with occasional shaking for two hours. Filter off the precipitate of magnesium ammonium phosphate upon a small filter and wash with ammonia water (one part 0. 96 sp. Gr. Ammonia to three parts water) until nearly free from sulphide. Pour 10 cc. Hydrochloric acid (one part HC1 sp. Gr. I. 20 to four parts water) into the flask, taking care that all
...of the precipitate adhering to the walls of the flask is dissolved, and then pour the acid through the filter, allowing the solution to run into a No. I beaker. Wash the flask and filter with 10 cc. More of the same acid. Add 3 cc. Of magnesia mixture to the filtrate, and then add ammonia slowly with constant stirring until present in slight excess. Add 10 cc. Ammonia sp. Gr. 0. 90, allow to stand in ice water for two hours, stirring the solution occasionally. Filter, and wash the precipitate with ammonia water until free from chlorides, and ignite with the usual precautions, weighing as Notes.

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