An Analysis of Molecular Volumes From the Point of View of the Lewis Langmuir Th

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An Analysis of Molecular Volumes From the Point of View of the Lewis Langmuir Th
Robert Norton Pease
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.. .. .. .. .. .. .. .. .. .. 652 631 21 3. 2 w-C 6 H 14 . .. .. .. .. .. .. .. .. .. .. .. .. .. .. 785 746 39 5. 0 w-C 7 Hi 6 . .. .. .. .. .. .. .. .. .. .. .. .. .. .. 919 861 58 6. 3 w-C 8 Hi8 . .. .. . . .. .. .. .. .. .. . . .. .. .. .. 1057 976 81 7. 7 (CH 3 ) 2 CH. CH 2 CH 3 . .. .. .. .. .. .. .. .. .. 641 631 10 1. 6 (CH 3 ) 2 CH. CH(CH 3 ) 2 . .. .. .. .. .. .. .. .. 745 746 1 0. 1 (CH 3 ) 2 CH. CH 2 CH 2 CH(CH 3 ) 2 . .. .. .. .. . 1025 976 49 4. 8 For the straight chain compounds,... the percentage by which the ob- served values exceed the calculated steadily increases, with increasing number of atoms. The branched chain isomers have volumes smaller than the straight chain and therefore nearer the calculated values. It is of interest to note that that compound in which the relative amount of departure from the straight chain is greatest, namely, di-0-propyl, H. CH, has a volume almost identical with that calculated (745 CH observed; 746 calculated). Ring Structures. It is of interest to find what values are obtained for ring structures.

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