An Attempt to Establish the First Principles of Chemistry By Experiment volume
An Attempt to Establish the First Principles of Chemistry By Experiment volume
Thomas Thomson
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But, if we compare Gmelin's analysis of car- bonate of lithia with his analysis of the sulphate, it will be evident that they cannot be quite ac- * Gilbert'* Annalen, IJX, 238. L1THIA AND LITHIUM. - 265 curate. The fused carbonate he found a com- pound of Carbonic acid 54-46 or 2-75 Lithia 45-54 - 2-2995 100-00 So that the atomic weight of lithia, by his analy- sis of the sulphate, is 2*416, while by the analysis of the carbonate it is only 22995- This dis- cordancy would render it hazardous to... employ Gm elm's analysis for the determination of the atomic weight of this alkali. Stromeyer's analysis is more recent than those of the three above named chemists ; and it comes nearer the truth than any of the others. * 100 parts of the crystals contain (according to him) 13 parts of water, and the anhydrous salt (cor- recting the calculations) is a compound of Sulphuric acid 68*977 or 5 Lithia 31-023 - 2-2488 100 The water, when reduced to the atomic propor- tions, is 1*083, or very nearly one atom.
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