An Elementary Treatise On Qual. Chemistry Analysis

Cover An Elementary Treatise On Qual. Chemistry Analysis
An Elementary Treatise On Qual. Chemistry Analysis
J. F. Sellers
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2. HgS precipitates black silver sulphide, AggS, sol- uble in boiling HNOg.
3. NH4OH precipitates brown silver oxide, AggO, soluble in excess of reagent.
4. NaOH gives similar results to NH^OH, except that the precipitate is not soluble in excess of reagent.
6. K2Cr04 precipitates dark-red silver chromate, AggCrO^, soluble in hot HNOg and in NH4OH.
6. Metallic copper deposits metallic silver on its surface.
7. Reducing flame on charcoal with NagCOg, or, better, with the fusion mixture of NagCOg
... and KgCOg, gives a metallic silver bead.
NajCOg acts partly as a flux, thus making possible the ioniza- tion of AgNOg and NagCOg, and partly as an active chemical agent. The following reactions occur here: — 2 AgNOg + Na^COg = Ag^COg 4- 2 NaNOg ; AgjjCOg 4- heat = Ag^O + CO^ ; 2Ag20 4-C=4Ag4-C02.
Mercurous Mercury, Hg' (salt for study, mercurous nitrate, Hg2(N03)2).
1. HCl precipitates white mercurous chloride or calo- mel, Hg2Cl2, soluble in hot HNOg ; insoluble in NH^OH, forming a black substance.


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