An Introduction to Modern Therapeutics, Being the Croonian Lectures On the Relationship Between the Chemical Structure And Physiological Action in Relation to the Prevention, Control, And Cure of Disease. Delivered Before the Royal College of Physicians I

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If in place of three atoms of chlorine we intro- duce three of iodine, each having a weight of 127, the molecular weight of the whole compound becomes 394, and in place of a permanent gas like marsh gas, or a heavy fluid like chloroform, we get a solid like iodoform.
The physical condition of the substance may be influenced by the number of atoms of other elements which combine with an alkyl as well as by their nature. Thus, when only one atom of hydrogen in methane, CH4, is replaced by chlorin
...e, the resulting monochlormethane, CH3CI, or methyl chloride, is a gas at ordinary temperatures, although it can be condensed by cold and pressure to a liquid which boils at 22°. Dichlormethane, or methylene chloride, CH2CI2, is a heavy liquid boiling at 41°, and the trichlor- methane, or chloroform, CHCI3, is a still heavier liquid, which boils at 61°. It appears, then, that we can increase the atomic , Io8 ACTION OF ALKYLS.
weight of an anaesthetic and render it more solid by adding on carbon to the alkyl, or by replacing hydrogen with heavier atoms like chlorine or iodine.


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