An Introduction to the Study of the Compounds of Carbon Or Organic Chemistry

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This is really the ammonium salt of carbamic acid, CO < ^ '. Ita formation is represented thus : — C02 + 2NH3 = CO<^. Now, remembering that carbon di sulphide is similar to carbon dioxide, and that ethyl-amine is similar to ammonia, we can readily understand the reaction which takes place when these two substances are brought together : — The product formed is the ethyl-ammonium salt of the acid OS < ^ ^, which may be called ethyl-sulpho-carbamic acid. When the ethyl- ammonium salt is treated with silver nitrate, the T^TTP TT corresponding silver salt, CS < ^ ^, is precipitated. And SAg finally, when this salt is distilled, it breaks up, yielding ethyl mustard-oil^ silver sulphide, and hydrogen sulphide : — 2 CS < NHC2H5 ^ 2 SC-NC2H5 -f H2S H- Agj^. SAg Ethyl mustard-oil is an oily liquid which does not mix with water. It has a very penetrating odor, and acts upon the mucous membranes of the eyes and nose in the same way as ordinary oil of mustard. The properties of the two are so much alike that one could be substituted for the other.

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