An Introduction to the Study of the Compounds of Carbon; Or, Organic Chemistry
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These substances, like the corresponding amines, form salts with acids, though not as readily. The hydroxide, tetraethyl- phosphonium hydroxide, P(C2H6)40H, is a very strong base, though not as strong as the corresponding nitrogen derivative.
The phosphines have one marked property which distin- guishes them from the amines, and that is their power to take up oxygen and form acids. Thus, ethylphosphine, PH2.C2H6, when treated with nitric acid, is converted into ethylphos phonic acid, PO(C2H6)(O...H)2, a dibasic acid, bearing to phosphoric acid the same relation that a sulphonic acid bears to sulphuric acid.
Note tor Student. — What is the relation? What other class of acids bears the same relation to carbonic acid ?
Diethylphosphine, PH(C2H5)2, yields diethylphosphinic acid, PO(C2H6)20H, and trie thy Iphosphine gives triethylphosphine oxide, (C2H6)3PO, when oxidized.
These compounds are not commonly met with, and do not play a very important part in the study of the compounds of carbon.
What to read after An Introduction to the Study of the Compounds of Carbon; Or, Organic Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Orndorff, W. R. (William Ridgely), 1862-1927 to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
These substances, like the corresponding amines, form salts with acids, though not as readily. The hydroxide, tetraethyl- phosphonium hydroxide, P(C2H6)40H, is a very strong base, though not as strong as the corresponding nitrogen derivative.
The phosphines have one marked property which distin- guishes them from the amines, and that is their power to take up oxygen and form acids. Thus, ethylphosphine, PH2.C2H6, when treated with nitric acid, is converted into ethylphos phonic acid, PO(C2H6)(O...H)2, a dibasic acid, bearing to phosphoric acid the same relation that a sulphonic acid bears to sulphuric acid.
Note tor Student. — What is the relation? What other class of acids bears the same relation to carbonic acid ?
Diethylphosphine, PH(C2H5)2, yields diethylphosphinic acid, PO(C2H6)20H, and trie thy Iphosphine gives triethylphosphine oxide, (C2H6)3PO, when oxidized.
These compounds are not commonly met with, and do not play a very important part in the study of the compounds of carbon.
What to read after An Introduction to the Study of the Compounds of Carbon; Or, Organic Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Orndorff, W. R. (William Ridgely), 1862-1927 to read onlineMoreLess
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