An Introduction to Theoretical And Applied Colloid Chemistry the World of Negl

Cover An Introduction to Theoretical And Applied Colloid Chemistry the World of Negl
An Introduction to Theoretical And Applied Colloid Chemistry the World of Negl
Carl Wilhelm Wolfgang Ostwald
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As 0. BUTSCHLI assumed and as proved in the ultramicroscopic investigations of R. ZSIGMONDY, many gels have a dual structure. They may contain ultramicroscopic particles which, in their turn, may coalesce to give rise to structures of microscopic dimensions. This behavior is common and entirely in harmony with the theory of gelation sketched above. A gel may, moreover, actually have a structure of micro- scopic dimensions without this being recognizable by microscopic or ultramicroscopic means.... As I emphasized before, a difference in degree of refraction is necessary to permit optical differentiation. In highly solvated colloids such differences may not appear. Nevertheless, a gel remains a gel even though it appears optically homogeneous, as in the case of gelatin. Sometimes through treatment THE CHANGES IN STATE OF COLLOIDS 103 with alcohol or other dehydrating agents, we can bring about refraction differences in such gels, which then make possible optical differentiation of structure.

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