An Introductory Course of Quantitative Chemical Analysis

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From the following data, calculate the percentages ofNa_{2}CO_{3} and NaOH in an impure mixture. Weight of sample, 1. 500grams; HCl (0. 5 N) required for phenolphthalein end-point, 28. 85 cc. ;HCl (0. 5 N) required to complete the titration after adding methylorange, 23. 85 cc.
!Answers!: 6. 67% NaOH; 84. 28% Na_{2}CO_{3}.
24. A sample of sodium carbonate containing sodium hydroxide weighs1. 179 grams. It is titrated with 0. 30 N hydrochloric acid, usingphenolphthalein in cold solution as an in
...dicator and becomes colorlessafter the addition of 48. 16 cc. Methyl orange is added and 24. 08 cc. Are needed for complete neutralization. What is the percentage of NaOHand Na_{2}CO_{3}?
!Answers!: 24. 50% NaOH; 64. 92% Na_{2}CO_{3}.
25. From the following data, calculate the percentages of Na_{2}CO_{3}and NaHCO_{3} in an impure mixture. Weight of sample 1. 000 gram;volume of 0. 25 N hydrochloric acid required for phenolphthaleinend-point, 26. 40 cc. ; after adding an excess of acid and boiling outthe carbon dioxide, the total volume of 0.


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