Analytical And Diagnostic Studies of An Icp-Excited Icp Fluorescence Spectrometer
Analytical And Diagnostic Studies of An Icp-Excited Icp Fluorescence Spectrometer
Krupa, Robert Joseph, 1960-
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Resonance Monochromator Detection Limits (mg/L) and Comparative Upper Linear Concentrations (mg/L) . Element ICP-ICP-RM Upper Linear Concentration LOD ICP-ICP-RM HCL-ICP-AFS^ ICP-AES Ba 1 5,000 ~ 100 Ca 1 3,000 90 20 Cr 2 5,000 500 150 Cu 3 5,000 75 150 Mg 3 10,000 20 50 Na 20 2,000 10 200 Zn 4 5,000 20 150 Reference 45. Reference 43. 43 spectral line begins to broaden, the emission spectrometer only views the line center. When self-absorption begins to occur, it affects the line center while t...he wings of the broadened line continue to increase in intensity, but this is not seen by the detector. A similar spectral bandpass limits the LDR of HCL-ICP-AFS; however, in this instance, the narrow source profiles of the HCLs are the limiting factor. The HCLs, because they are at low pressure and at a significantly lower trans- lational temperature than the atoms in the TCP, have a much narrower emission profile than the absorption profile of the atoms in the ICP. Therefore, even though a wide spectrometer (filter) bandpass can be employed without increasing the effect of spectral interferences, only the line center is being measured as in AES.
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