Application of Some General Reactions to Investigations in Organic Chemistry
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By means of ethylic bromacetate or ethylic iodacetate the group CH 2 . CO-OC 2 H 5 may be readily introduced into desoxybenzoi'n, but ethylic chloracetate is not suitable for this purpose. In many cases halogens may be removed from pyridine derivatives by means of sulphuric acid and iron filings; the method is successful in the case of iodolepidine, but fails in the case of the chloro-derivative.
The employment for alkylation purposes of di- methylic sulphate or diethylic sulphate, instead of m...ethylic iodide or ethylic iodide, avoids the necessity for the use of sealed tubes; the two sulphates are now readily accessible, and consequently, for both reasons, the method affords a welcome means of modifying one acid, hydriodic, by the substitution of another, sulphuric.
Since the preparation of fluorine compounds has MODIFICATION OF REACTIONS. 47 ceased to offer special difficulties, the question must be raised as lo their reactivity and the extent to which they may be advantageously employed for modifica- tion purposes.
What to read after Application of Some General Reactions to Investigations in Organic Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Dr Lassar Cohn to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
By means of ethylic bromacetate or ethylic iodacetate the group CH 2 . CO-OC 2 H 5 may be readily introduced into desoxybenzoi'n, but ethylic chloracetate is not suitable for this purpose. In many cases halogens may be removed from pyridine derivatives by means of sulphuric acid and iron filings; the method is successful in the case of iodolepidine, but fails in the case of the chloro-derivative.
The employment for alkylation purposes of di- methylic sulphate or diethylic sulphate, instead of m...ethylic iodide or ethylic iodide, avoids the necessity for the use of sealed tubes; the two sulphates are now readily accessible, and consequently, for both reasons, the method affords a welcome means of modifying one acid, hydriodic, by the substitution of another, sulphuric.
Since the preparation of fluorine compounds has MODIFICATION OF REACTIONS. 47 ceased to offer special difficulties, the question must be raised as lo their reactivity and the extent to which they may be advantageously employed for modifica- tion purposes.
What to read after Application of Some General Reactions to Investigations in Organic Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Dr Lassar Cohn to read onlineMoreLess
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