Applied Colloid Chemistry General Theory
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News, 108, 178 (1913).
126 APPLIED COLLOID CHEMISTRY A comparatively recent technical development in contact catalysis is the hardening of oils, by the conversion of oleic acid or olein, for instance, into stearic acid or stearin by the action of hydrogen on the liquid unsaturated oil in presence of a suitable catalytic agent. 1 In 1908 Paal 2 proposed using a colloidal metal as the catalytic agent at ordinary temperatures. Colloidal solutions of platinum, palladium, osmium, and iridium have be...en made, of which the palladium hydrosol appears to possess the greatest value. When hydrogen at ordinary temperatures is passed into glycerides of the unsaturated fatty acid to which some palladium hydrosol has been added, reduction takes place. It is more satisfactory, however, to precipitate the metal on an inert base such as magnesia or kieselguhr.
A cheaper and apparently better method is to use nickel as a catalytic agent for the hydrogenation of liquid, unsaturated acids, the reduction taking place at about 250-300.
What to read after Applied Colloid Chemistry General Theory?
You can find similar books in the "Read Also" column, or choose other free books by Wilder D Wilder Dwight Bancroft to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
News, 108, 178 (1913).
126 APPLIED COLLOID CHEMISTRY A comparatively recent technical development in contact catalysis is the hardening of oils, by the conversion of oleic acid or olein, for instance, into stearic acid or stearin by the action of hydrogen on the liquid unsaturated oil in presence of a suitable catalytic agent. 1 In 1908 Paal 2 proposed using a colloidal metal as the catalytic agent at ordinary temperatures. Colloidal solutions of platinum, palladium, osmium, and iridium have be...en made, of which the palladium hydrosol appears to possess the greatest value. When hydrogen at ordinary temperatures is passed into glycerides of the unsaturated fatty acid to which some palladium hydrosol has been added, reduction takes place. It is more satisfactory, however, to precipitate the metal on an inert base such as magnesia or kieselguhr.
A cheaper and apparently better method is to use nickel as a catalytic agent for the hydrogenation of liquid, unsaturated acids, the reduction taking place at about 250-300.
What to read after Applied Colloid Chemistry General Theory?
You can find similar books in the "Read Also" column, or choose other free books by Wilder D Wilder Dwight Bancroft to read onlineMoreLess
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