Beiträge Zur Wissenschaftlichen Medicin Und Chemie: Festschrift Zu Ehren Des ...

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Beiträge Zur Wissenschaftlichen Medicin Und Chemie: Festschrift Zu Ehren Des ...
Ernst Salkowski
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Digitized by Google On Bilirubin, the red coloring-matter of the bile. 299 likely, a twin structure, which is not apparent from their external form. Some of those with broken ends show strong double refraction and Sharp extinction at an angle varying from 2.5^ to 12^. The crystals are either monoclinic or triclinic as shown by this extinction angle".
b) Solubility.
Thudichum gives the solubility of bilirubin in Chloroform as one part in 586 parts of chloraforra, while Küster states it as one pa
...rt in 567 parts of Chloroform. Neither investigator describes his method of determining the solubility or indeed gives any details. Pure, crystallized bilirubin dissolves very slowly in Chloroform, even when boiled with the solvent for some timc. In ordcr to prepare a saturated Solution of the substance, we found it was best to boil the bilirubin with Chloroform (using an upright condenser) for 8 to 12 hours, filter the Solution distil oflf a portion of the solvent on the water-bath and let the Solution stand tili next day.

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