Brief Course in Qualitative Analysis

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KCNS or NH.CNS produces Fe^CCNSX- Blood-red solution.
Not destroyed by HCl.
80. NaQHsO, in neutral solutions or those slightly acid with HC^HjOj produces Fe2(C2H302)e, which is deep red. On being boiled, reddish brown basic ferric acetates are precipitated.
81. See 74.
82. Reducing agents, such as HjS, SOj and nascent hydro- gen, convert ieritc into ferrous compounds.
Ai,UMiNiUM. Al. Valence = 111.
Use preferably Al^CSOJa.
83. (NHJjS and fixed alkaline sulphides precipitate Al2(OH)8 with the ev
...olution of H^S gas.
White, flocculent.
Insoluble in excess of reagent.
84. Alkaline hydroxides precipitate AljCOH)^.
White, flocculent.
Slightly soluble in excess of NH4OH (rendered less soluble by the presence of ammonium salts).
Easily soluble in excess of NaOH and KOH; hot or cold.
85. BaCOs suspended in water precipitates Ali(OH)e with the evolution of COj.
86. Heated with blowpipe on charcoal, aluminium com- pounds yield, when moistened with CoCNOa), and again ignited, a sky-blue infusible mass.


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