Capability of D2 Spectrometry for Detecting Raman Scattering
Capability of D2 Spectrometry for Detecting Raman Scattering
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Figures 18 and 19, and Tables III and IV) .
68 data which have the same frequency difference around the laser center frequency, as well as unmatched lines which are Raman derived. On these figures, Stokes lines appear to be "shifted" from the anti-Stokes lines, but fit expected pat- terns for Raman spectra, while the interference patterns do not.
Apparently the origin of the interfering lines, there- fore, is not Raman scattering, nor Rayleigh scattering of the neon laser line background. The m...ost plausible assumption is that the particular grating has a type of "ghost" which results from a periodic error in the otherwise regular spacing between the ruled lines. This effect is generally small, and is not objectionable. It has an apparent amplitude here of about 3 1:10 to allow for the Rayleigh line to be the size of the Raman line. This type of "ghost" and others have been long known [25,26].
The grating "ghost effect" should vary with the particu- lar grating in use, but any effect should be reduced sub- o stantially if an optical blocking filter for 6328 A, or the excitation frequency, were inserted between the exit slit and the photomultiplier.
What to read after Capability of D2 Spectrometry for Detecting Raman Scattering?
You can find similar books in the "Read Also" column, or choose other free books by Kilpatrick, Wallace Dorman, 1920- to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
Figures 18 and 19, and Tables III and IV) .
68 data which have the same frequency difference around the laser center frequency, as well as unmatched lines which are Raman derived. On these figures, Stokes lines appear to be "shifted" from the anti-Stokes lines, but fit expected pat- terns for Raman spectra, while the interference patterns do not.
Apparently the origin of the interfering lines, there- fore, is not Raman scattering, nor Rayleigh scattering of the neon laser line background. The m...ost plausible assumption is that the particular grating has a type of "ghost" which results from a periodic error in the otherwise regular spacing between the ruled lines. This effect is generally small, and is not objectionable. It has an apparent amplitude here of about 3 1:10 to allow for the Rayleigh line to be the size of the Raman line. This type of "ghost" and others have been long known [25,26].
The grating "ghost effect" should vary with the particu- lar grating in use, but any effect should be reduced sub- o stantially if an optical blocking filter for 6328 A, or the excitation frequency, were inserted between the exit slit and the photomultiplier.
What to read after Capability of D2 Spectrometry for Detecting Raman Scattering?
You can find similar books in the "Read Also" column, or choose other free books by Kilpatrick, Wallace Dorman, 1920- to read onlineMoreLess
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