Catalysis in Organic Chemistry
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CH 2 . C 6 H 6, a well crystallized solid. 25 521. Nitriles. Copper can transform nitriles into primary and secondary amines 26 in the same manner that nickel does. It acts 22 SABATIEB and SENDERENS, Compt. Rend. , 132, 1255 (1901).
23 SABATIER and SENDERENS, Compt. Rend. , 130, 1559 (1900).
24 SABATIER and SENDERENS, Compt. Rend. , 135, 87 (1902). 26 SABATIER and SENDERENS, Compt. Rend. , 135, 88 (1902).
26 SABATIER and SENDERENS, Compt. Rend. , 140, 482 (1905) and Bull. Soc. Chim. (3), 33, 37...1 (1905), 522 CATALYSIS IN ORGANIC CHEMISTRY 184 similarly on the carbyl-amines? 7 but its action is less rapid than that of nickel.
522. Aliphatic Aldehydes and Ketones. Below 200, copper can transform these slowly into the alcohols, but the inverse action usually preponderates and this makes the use of copper less advantageous.
Furthermore, copper is incapable of transforming the oxides of carbon into methane or of hydrogenating the aromatic nucleus.
523. Aromatic Ketones. When benzophenone is hydrogenated at 350 over copper with a violet tint, prepared by the reduction of the hydroxide (59), diphenyl-methane is formed directly.
What to read after Catalysis in Organic Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Sabatier, Paul, 1858-1928 to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
CH 2 . C 6 H 6, a well crystallized solid. 25 521. Nitriles. Copper can transform nitriles into primary and secondary amines 26 in the same manner that nickel does. It acts 22 SABATIEB and SENDERENS, Compt. Rend. , 132, 1255 (1901).
23 SABATIER and SENDERENS, Compt. Rend. , 130, 1559 (1900).
24 SABATIER and SENDERENS, Compt. Rend. , 135, 87 (1902). 26 SABATIER and SENDERENS, Compt. Rend. , 135, 88 (1902).
26 SABATIER and SENDERENS, Compt. Rend. , 140, 482 (1905) and Bull. Soc. Chim. (3), 33, 37...1 (1905), 522 CATALYSIS IN ORGANIC CHEMISTRY 184 similarly on the carbyl-amines? 7 but its action is less rapid than that of nickel.
522. Aliphatic Aldehydes and Ketones. Below 200, copper can transform these slowly into the alcohols, but the inverse action usually preponderates and this makes the use of copper less advantageous.
Furthermore, copper is incapable of transforming the oxides of carbon into methane or of hydrogenating the aromatic nucleus.
523. Aromatic Ketones. When benzophenone is hydrogenated at 350 over copper with a violet tint, prepared by the reduction of the hydroxide (59), diphenyl-methane is formed directly.
What to read after Catalysis in Organic Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Sabatier, Paul, 1858-1928 to read onlineMoreLess
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