Catalysis in the Interaction of Carbon With Steam And With Carbon Dioxide
Catalysis in the Interaction of Carbon With Steam And With Carbon Dioxide
Harvey a Harvey Alexander Neville
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It was thought that the decrease in the activity of the nickel as catalyst might be due to surface oxidation by the steam. If this were the case, it should recover its activity when again reduced with hydrogen. The steam generation was stopped and a stream of hydrogen was substi- tuted for it. When steam was again passed through the charge, the evolu- tion of gas was at the rate of 4 cc. Per minute, and fell during an hour to an apparently constant value at 2. 6 cc. Per minute. It is probable t...hat the nickel had either become coated over with a deposit of carbon due to decomposition of carbon monoxide, a reaction catalyzed by nickel, or that it had been agglomerated, by being heated at 570 for a considerable time, into larger particles which had much less catalytic activity. Carbon Dioxide on Carbon. Materials similar to those studied in the preceding steam-carbon reaction were used as catalysts for this reaction. The results of these experiments are recorded in Table II and graphically represented in Fig.
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