Chemical Lecture Experiments

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By the action of phosphorus trichloride on water. Water reacts energetically with phosphorus trichloride, form- ing phosphorous acid and hydrochloric acid. The hydro- chloric acid liberated is to a large extent absorbed by the water used in the operation, though, by boiling, the excess of gas may be driven off, leaving a solution containing phos- phorous and hydrochloric acids.
A few cubic centimeters of phosphorus trichloride are al- lowed to fall from a dropping-funnel into 20 cc. Of water in
... a small distilling-flask. The dropping-funnel is inserted in the neck of the flask in a one-holed rubber stopper, and the side tube of the flask should be provided with a rubber tube to conduct away the hydrochloric acid fumes that are formed. As the phosphorus trichloride conies in contact with the water, a vigorous reaction takes place and large quantities of hydrochloric acid are liberated. On removing the dropping- funnel and corking the neck of the flask, the contents may be brought to a boil and the excess of hydrochloric acid driven off.

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