Chemical Reactions And Their Equations

Cover Chemical Reactions And Their Equations
Chemical Reactions And Their Equations
Ingo W D Ingo Waldemar Dagobert Hackh
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In other words, the permanganate (Mn0 4 ~) can be any soluble per- manganate, either of sodium, potassium, etc. ; the ferrous salt can be any soluble salt, either sulfate, chloride, nitrate, etc. ; and the acid can be either HC1, H 2 SO 4, HNO 3, etc.
Problem 2. A nitrite solution is oxidized to a nitrate solution by an acidified bichromate solution : First, the valence numbers are written under the ions NO 2 - - +- Cr, O 7 - = N0 3 - - f 2Cr+++ 3 2(6) 5 2(3) = 12 j = 6 The nitrogen of the nitr
...ite therefore has been oxidized from 3 to 5 increased 2 steps. The chromium of the chromate has been reduced from 12 to 6 decreased 6 44 CHEMICAL REACTIONS AND THEIR EQUATIONS steps. To balance the factors are reversed, 6(2) = 2(6), therefore, 6NO 2 ~ + 2Cr 2 O 7 = 6NO 3 - + 4Cr+++ The proportion 6 : 2 can in this case be simplified to 3 : 1 and the unfinished equation becomes: 3NO 2 - + O 2 O 7 = 3NO 3 - + 2Cr+++ Second, the charges are counted on both sides, thus on the left there are 3 nitrites = 3 negative charges 1 bichromate = 2 negative charges a total of 5 negative charges on the right there are 3 nitrates = 3 negative charges 2 chromic ions = 6 positive charges a total of 3 positive charges To balance +3 and 5 requires either 8 positive charges to the left, or 8 negative charges to the right.

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