Chemistry for Engineers And Manufacturers. a Practical Text-Book 2
Chemistry for Engineers And Manufacturers. a Practical Text-Book 2
Bertram Blount
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When an electric current is passed through a solution of this salt, chlorine is evolved at the anode, and magnesia and hydrogen at the cathode. If means be taken for the suppression of the hydrogen, the chlorine acting on the magnesia yields a solution of magnesium hypochlorite, which may be applied similarly to the chloride of lime usually employed. The liquor, after it has done its work of bleaching, and its oxidising effect has been expended, is returned to the decomposing cells and again el...ectrolysed. As magnesium hypochlorite is more unstable than calcium hypochlorite, free hypochlorous acid is more readily derived from the former, and thus the rate of bleaching is increased. The process, though said to be in successful operation in France, has proved a failure in this country. For the production of a full white "market bleach'' it ia frequently necessary to correct the yellow tint of the bleached goods by the addition of a small quantity of ultramarine. It must be remembered that the oxidising action of chloride of lime is not without effect on the cellulose itself, so that the use of a strong solution of bleaching powder is not permissible.
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