Chemistry in the Service of Man

Cover Chemistry in the Service of Man
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This great difference in the rate of reaction we shall be inclined to attribute to differences in the chemical affinity, and in so doing we shall be right, but only partly right ; for when one studies the process of chemical change more fully, it is found that the rate of a reaction does not depend merely on chemical affinity, but also on a number of other factors. Of these factors, one of the most im- portant is the concentration of the reacting substances, that is, the amount of the substance...s in a given volume. We shall be able to understand this more readily, if we fix VELOCITY OF REACTIONS AND CATALYSIS 91 our attention, for the present, on reactions between gaseous substances. When a substance is in the state of a gas, its molecules are supposed, according to the kinetic theory of matter, to be moving about with great velocity in all directions, and combination or reaction between two substances, A and B, can take place only when molecules of A and B collide or come within each other's sphere of influence.

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