Chemistry of the Carbon Compounds: Or, Organic Chemistry
Chemistry of the Carbon Compounds: Or, Organic Chemistry
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Its derivatives, containing alkyl or phenyl groups attached to the N>atom, are similarly produced by the action of primary amines upon acetophenone-acetoacetic ester (p. 546).
(I, 4).Diphenylpyrrol-j3^arboxylic Acid, C4H(CjH5),(NH).COjH, from acetophenone-benzoyl acetic ester and ammonia (p. 495), melts at 261° {Berichte, ai. 3060).
KETONIC ACIDS.
a-PyrroylCarbozylic Acid,C4H,(NH).C0.C0,H, Pyrryl GLyoxylic Acid, is produced by the oxidation of a-pyrryl methyl ketone (p. 544) with alkaline po- t...assium permanganate {Berichte, 17, 2949). It crystallizes from water in yellow needles, melting with decomposition at 74-76^. They become anhydrous when placed over sulphuric acid. The anhydrous acid, from benzene, consists of yellow needles, decomposing about 1 14^ Ferric chloride imparts an intense red color to the aqueous solution. When fused with caustic potash, it becomes a-pyrrol-car- boxylic acid {Berichte^ 19, 1957).
Pyrryl-mcthyl-ketone Carboxylic Acid, C4H,(NH)^^^-^», Accto- pyrrol carboxylic acid.
What to read after Chemistry of the Carbon Compounds: Or, Organic Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Victor Von Richter to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
Its derivatives, containing alkyl or phenyl groups attached to the N>atom, are similarly produced by the action of primary amines upon acetophenone-acetoacetic ester (p. 546).
(I, 4).Diphenylpyrrol-j3^arboxylic Acid, C4H(CjH5),(NH).COjH, from acetophenone-benzoyl acetic ester and ammonia (p. 495), melts at 261° {Berichte, ai. 3060).
KETONIC ACIDS.
a-PyrroylCarbozylic Acid,C4H,(NH).C0.C0,H, Pyrryl GLyoxylic Acid, is produced by the oxidation of a-pyrryl methyl ketone (p. 544) with alkaline po- t...assium permanganate {Berichte, 17, 2949). It crystallizes from water in yellow needles, melting with decomposition at 74-76^. They become anhydrous when placed over sulphuric acid. The anhydrous acid, from benzene, consists of yellow needles, decomposing about 1 14^ Ferric chloride imparts an intense red color to the aqueous solution. When fused with caustic potash, it becomes a-pyrrol-car- boxylic acid {Berichte^ 19, 1957).
Pyrryl-mcthyl-ketone Carboxylic Acid, C4H,(NH)^^^-^», Accto- pyrrol carboxylic acid.
What to read after Chemistry of the Carbon Compounds: Or, Organic Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Victor Von Richter to read onlineMoreLess
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