Compositional Analysis of Glass Surfaces And Their Reaction in Aqueous Environments

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Compositional Analysis of Glass Surfaces And Their Reaction in Aqueous Environments
Pantano, Carlo George
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This hypothesis was tested as follows. After reacting the glass surface for one hour in H „ as described above in Figure 26, the solution pH was 7.7. The glass was quickly rinsed, and re- exposed for one hour to high-purity water. If the solution pH which is now lowered to 6.8 is significantly determining the surface composition profile, a change in the profile could result. In particular, one would expect increased preferential leaching of sodium and calcium at this more acidic pH. This should... be reflected in both the composi- tion profile and solution analysis. Figure 27 compares the Na and Ca profiles measured before and after this solu- tion replenishment test. The peak heights are normalized to the oxygen peak height. These peak height ratios are 119 c E jc O.
0> CC c o _2 o (/) o 0> £ "O TJ w. -j 0) « Q. o -o ' ' c

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