Double Resonance Spectroscopy As a Diagnostic Tool And Analytical Technique for Atomic Spectroscopy

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For these operating conditions, i.e., in the absence of laser induced noise and furnace emission noise, the value of three times the standard deviation of the noise of the detection system at the three ultraviolet wave- lengths was 150 uV. It is worth emphasizing here that the noise shown in Figure 4-4 at 405.783 nm is not that occurring during the atomization stage of lead (performed at 1800°C) but during the final cleaning stage (2500°C). Therefore, the lead peak is well separated from the no...ise shown.
However, when the laser beams were admitted into the system, without operating the furnace, the noise is increased considerably as shown in Figures 4-5 and 4-6. The limiting noise shown in these figures was a result of leakage of some laser radiation into the 97 10 mV (a) — *|5 s|«- Figure 4-4 Chart Recorder Tracings of the Furnace Emission Noise at the Four Fluorescence Wavelengths Investigated in this Work: a) 405.783 nm, b) 261.418 nm, c) 239.379 nm, and d) 216.999 nm ^^^■J*553£» rrnr 5 mV T 5 s (a) (b) Figure 4-5 Boxcar Output for Laser Induced Noise into the Detector System for Single Resonance Excitation at 283.


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