Eight Lectures On Theoretical Physics

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g., in the case of water).
V. Vaporization of a Solution of Volatile Substances.
{E. g., a Sufficiently Dilute Solution of Propyl Alcohol in Water.) The system, consisting of two phases, is represented by the following symbol: noTOo, niTOi, n2TO2, • • • | no'mo', ni'mi, n^'mi', • ■ -, wherein, as above, the figure refers to the solvent and the figures 1, 2, 3 • • • refer to the various molecular complexes of the dissolved substances. By the addition of primes in the case of the molecular weight
...s (too', TOi', mi.' • • • ) the possibility is left open that the various molecular complexes in the vapor may possess a different molecular weight than in the liquid.
Since the system here considered may experience various sorts of changes, there are also various conditions of equilibrium to fulfill, each of which relates to a definite sort of transformation.
Let us consider first that change which consists in the vaporiza- tion of the solvent. In accordance with our scheme of notation, the following conditions hold : j'o = — 1, vi= 0, Vi = 0, ■•■ vo' = --;, vi = 0, v^' = 0, ■ • •, Too 34 SECOND LECTUEE.


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