Electric Smelting And Refining: the Extraction And Treatment of Metals By Means of the Electric Current

Cover Electric Smelting And Refining: the Extraction And Treatment of Metals By Means of the Electric Current
Electric Smelting And Refining: the Extraction And Treatment of Metals By Means of the Electric Current
W Wilhelm Borchers
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tBerg- und hUUenmanTiviche Zeitung, 1891, p. 393.
§ Siemens & Halske (German Patent 66,592).
(I Cf, Mylius and Fromm, Berichte d. detUaehen, chem, OeselUdunfl, vol* xxvii. , p. 630.
IT The precipitate contains nitrate and requires further investigation.
Digitized by V^OO^ It!
ZINC. 399 alone and without oxidising agents, gave a smooth white deposit thronehont.
*'(3) The spongy zinc is produced only when the conditions are favourable to the formation of zinc oxide. A 10 per cent, solution of zin
...c sulphate, which was intentionally made some- what turbid by precipitated oxide, gave a grey spongy zinc upon a sheet-zinc cathode after five minutes of electrolysis with a current of 1 ampere per sq. dm. [0*0645 amp. per sq. in.]. The action, however, was only observable at the level of the upper surface of the liquid.''^ "(4) The formation of spongy zinc is determined by the presence of foreign metals which produce an oxidation of the metal through electro-chemical action. Nahnsen has already proved many times that the zinc becomes spongy most readily when the solution contains such impurities as copper, arsenic, antimony, &c.

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