Electro Chemistry

Cover Electro Chemistry
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0-0003 2 Nico inic acid C 5 H 4 N. COOII ...... 0-0014 3 Isonicotinic acid C 5 H 4 N. COOH ..... . O'oon The decrease is much greater when the carboxyl is attached to a carbon atom adjacent to the nitrogen atom than in any other case.
Dibasic Organic Acids. The equations representing the ionisation of a dibasic acid AH 2) are AH 2 ^t AH' + H- AH' ^ A" + H- It will be seen from the numbers which follow that the ionisation-constant corresponding to the second equation (which will be called the se
...cond ionisation-constant) is 1 Zeitschr. Phys. Ckem. , 19. 456.
2 Ebersbach, Zeitschr. Phys. Chem. , 11. 608. Ostwald, loc. Cit.
H2 ELECTRO-CHEMISTRY always very much smaller than the constant corresponding to the first stage of ionisation (or first ionisation-constant). Moreover, the second stage of ionisation is retarded by the action of the hydrogen ions which result from the first stage of ionisation, in accordance with the law of mass action, so that, except in dilute solution, the ionisation proceeds practically no farther than the first stage.


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