Electrochemical Investigation of Liquid Amalgams of Thallium Indium Tin Zinc

Cover Electrochemical Investigation of Liquid Amalgams of Thallium Indium Tin Zinc
Electrochemical Investigation of Liquid Amalgams of Thallium Indium Tin Zinc
Theodore William Richards
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Moreover, the dilution must be carried out in an indifferent gas in order to avoid oxidation with its attending heat effect.
Nevertheless, in spite of these difficulties the attempt was made to determine the heat of dilution in the cases of the more concentrated amal- gams of thallium and indium. 1226 grams of a I per cent thallium amal- gam were diluted with an equal bulk of mercury and found to cause a rise of 0. 015 in a calorimetric system having a heat capacity of 431 mayers. On further di
...luting by an equal bulk of mercury the mixture resulting from this first experiment, the increased system (having now a heat capacity of 762 mayers) was raised through only 0. 002. These effects were in the expected direction, but not of the expected magnitude.
The experiments were conducted in the apparatus of Richards and Forbes, in which the mixing was conducted by a clock-work stirrer. Lack of time had prevented the proposers of this apparatus from testing it thoroughly. Our present experience indicates that the clock-work stirring was inadequate, and hence that an inadequate change of temperature must have been observed in all cases.


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