Electrochemistry of Organic Compounds
Electrochemistry of Organic Compounds
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131 a high anode current density, xanthic supersulphide, or ethyl dioxysulphocarbonate, as might be expected: /OC 2 H 5 /OC 2 H 5 C 2 H 5 (\ 2CSC S +2K.
\SK X S- $/ Potassium Methyl-, Isobutyl-, and Isoamylxanthate behave analogously (Schall and Kraszler 1 ). They are converted at the anode into the corresponding dithiondisulphides RCSS SSCR.
These are non-crystallizable oils.
Ammonium Dithiocarbamate is converted with difficulty into thiuramdisulphide : (NH 2 CS)S-S(SCNH 2 ); the conditions un...der which this takes place have not yet been explained.
Diethylammonium Diethyldithiocarbamate is said to give at the anode tetraethylthiuramdisulphide : [(C 2 H 5 ) 2 NCS]S - S[SCN(C 2 H 5 ) 2 ]. Potassium Ethyltrithiocarbonate gives dithiondisulphide : (C 2 H 5 SC)S-S(CSC 2 H 5 ).
Potassium Phenylsulphocarbazinate, C 6 H 5 NH NHCSSK, gives (Schall and Kraszler 2 ) no disulphide, but diphenyl- thiocarbazide : CS(NH-NHC 6 H 5 ) 2 .
1 Zeitschr. F. Elektrochemie 5, 225 (1898). 2 1. C.
CHAPTER IV.
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You can find similar books in the "Read Also" column, or choose other free books by Walther Lb to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
131 a high anode current density, xanthic supersulphide, or ethyl dioxysulphocarbonate, as might be expected: /OC 2 H 5 /OC 2 H 5 C 2 H 5 (\ 2CSC S +2K.
\SK X S- $/ Potassium Methyl-, Isobutyl-, and Isoamylxanthate behave analogously (Schall and Kraszler 1 ). They are converted at the anode into the corresponding dithiondisulphides RCSS SSCR.
These are non-crystallizable oils.
Ammonium Dithiocarbamate is converted with difficulty into thiuramdisulphide : (NH 2 CS)S-S(SCNH 2 ); the conditions un...der which this takes place have not yet been explained.
Diethylammonium Diethyldithiocarbamate is said to give at the anode tetraethylthiuramdisulphide : [(C 2 H 5 ) 2 NCS]S - S[SCN(C 2 H 5 ) 2 ]. Potassium Ethyltrithiocarbonate gives dithiondisulphide : (C 2 H 5 SC)S-S(CSC 2 H 5 ).
Potassium Phenylsulphocarbazinate, C 6 H 5 NH NHCSSK, gives (Schall and Kraszler 2 ) no disulphide, but diphenyl- thiocarbazide : CS(NH-NHC 6 H 5 ) 2 .
1 Zeitschr. F. Elektrochemie 5, 225 (1898). 2 1. C.
CHAPTER IV.
What to read after Electrochemistry of Organic Compounds?
You can find similar books in the "Read Also" column, or choose other free books by Walther Lb to read onlineMoreLess
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