Electrolysis And Electrosynthesis of Organic Compounds

Cover Electrolysis And Electrosynthesis of Organic Compounds
Electrolysis And Electrosynthesis of Organic Compounds
Walther Lb
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OF AROMATIC COMPOUNDS. 7 1 condensation products of the same with the nitro- aldehyde present. The nitro-benzylidene-aldehydo- phenyl-hydroxylamines are thus formed : + 4H = H ' + C H '\NHOH.
2.
/CHO U H \ /O\ \N - CH. C 6 H 4 . NO 9 .
p-Nitro-benzylidene-p-aldehydo-phenyl-hydroxylamine y C. CHO C. NO, # \ / ^ HC CH HC CH I II II I ' HC CH HC CH V/ /o\ \ c // _N -- CH- may thus be prepared from p-nitro-benzaldehyde.
From m-nitro-benzaldehyde an analogous compound is formed.
Gattermann, 1 on red
...ucing several aromatic nitro- ketones, obtained the corresponding derivatives of amido-phenols.
By a similar treatment amido-oxy-acetophenone, 1 Chem. Ber. , 29, 3034.
72 ELECTROLYSIS AND ELECTROS YNTHESIS is formed from m-nitro-acetophenone ; amido-oxy-ben zophenone, from m-nitro-benzophenone ; and amido-oxy-phenyl-p- tolylketone, from m-nitro-phenyl-p-tolylketone.
The process which Straub ' employs to prepare hydrazo-compounds from nitro-hydrocarbons is yet to be mentioned. The chief feature of his experiments is that the original material and all intermediate products are retained in solution during the electroly- sis by the selection of a suitable solvent, and the hydrazo-compounds are withdrawn from the action of the current by precipitation.


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