Electrolyte Behavior in Solvents of High Dielectric Constant
Electrolyte Behavior in Solvents of High Dielectric Constant
Butler, Richard Alan
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The finished electrodes were stored in water. All hydrogen electrodes were cleaned in 50% (vol.) "aqua regia" (3 parts concentrated HC1 to 1 part concentrated HNOo) and replatin- ized after each use . Equipment and Procedures The cells used for measurements in H 9 0/NMA solvent mixtures were of the type commonly used by Bates and co- workers and first described by Gary, Bates and Robinson' 77 ^ . This cell is shown diagrammatically in Figure 2. It is of all-glass construction with the exception... of Teflon stopcocks The cell has the advantage that the entering H2 gas is satur- ated with solvent in the first three stages which contain the same solution as the electrode compartments. This presatur- ation prevents a change in the solution composition around the Pt;H2 electrode which might otherwise be caused by the flowing gas . All solutions were de-aerated by bubbling purified H 2 gas through them for at least one hour prior to filling the cells. The cells were filled without allowing the solution to come into contact with air.
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