Electrolyte Behavior in Solvents of High Dielectric Constant
Electrolyte Behavior in Solvents of High Dielectric Constant
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The finished electrodes were stored in water. All hydrogen electrodes were cleaned in 50% (vol.) "aqua regia" (3 parts concentrated HC1 to 1 part concentrated HNOo) and replatin- ized after each use .
Equipment and Procedures The cells used for measurements in H 9 0/NMA solvent mixtures were of the type commonly used by Bates and co- workers and first described by Gary, Bates and Robinson' 77 ^ .
This cell is shown diagrammatically in Figure 2. It is of all-glass construction with the exception... of Teflon stopcocks The cell has the advantage that the entering H2 gas is satur- ated with solvent in the first three stages which contain the same solution as the electrode compartments. This presatur- ation prevents a change in the solution composition around the Pt;H2 electrode which might otherwise be caused by the flowing gas .
All solutions were de-aerated by bubbling purified H 2 gas through them for at least one hour prior to filling the cells. The cells were filled without allowing the solution to come into contact with air.
What to read after Electrolyte Behavior in Solvents of High Dielectric Constant?
You can find similar books in the "Read Also" column, or choose other free books by Butler, Richard Alan to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
The finished electrodes were stored in water. All hydrogen electrodes were cleaned in 50% (vol.) "aqua regia" (3 parts concentrated HC1 to 1 part concentrated HNOo) and replatin- ized after each use .
Equipment and Procedures The cells used for measurements in H 9 0/NMA solvent mixtures were of the type commonly used by Bates and co- workers and first described by Gary, Bates and Robinson' 77 ^ .
This cell is shown diagrammatically in Figure 2. It is of all-glass construction with the exception... of Teflon stopcocks The cell has the advantage that the entering H2 gas is satur- ated with solvent in the first three stages which contain the same solution as the electrode compartments. This presatur- ation prevents a change in the solution composition around the Pt;H2 electrode which might otherwise be caused by the flowing gas .
All solutions were de-aerated by bubbling purified H 2 gas through them for at least one hour prior to filling the cells. The cells were filled without allowing the solution to come into contact with air.
What to read after Electrolyte Behavior in Solvents of High Dielectric Constant?
You can find similar books in the "Read Also" column, or choose other free books by Butler, Richard Alan to read onlineMoreLess
Read book Electrolyte Behavior in Solvents of High Dielectric Constant for free
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