Electrolytic Preparations. Exercises for Use in the Laboratory By Chemists And Electro-Chemists
Electrolytic Preparations. Exercises for Use in the Laboratory By Chemists And Electro-Chemists
Karl Elbs
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They are first polished with wet sand, then electrolytically oxidized in 20 per cent, sulphuric acid (accumulator acid) with a current density of % amperes per 100 sq. cms. during half an hour, afterwards rinsed in cold water, im- mersed in boiling water for some minutes, washed with boiling alcohol, and dried quickly in a current of air. In this condition the cathodes can be preserved unaltered. With the exception of the polishing with sand this treat- ment is advantageously repeated after eac...h experiment. The same treatment is suitable once even for the anodes, but does not need to be repeated ; it is sufficient from time to time, after using, to soak them in water, wash them over, and quickly dry them. Foreign metals can easily be intro- duced by means of the porous pot ; the new cells are there- fore digested first with dilute caustic soda, then with water, and afterwards with hydrochloric acid of i*oa to 1-03 sp. gr., each time for one to two days, and finally with water for a whole week.
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