Electron Spin Resonance And Optical Spectroscopy of Hydrocarbon Radicals At 4°k in Raregas Matricas / By Keith Ingram Dismuke
Electron Spin Resonance And Optical Spectroscopy of Hydrocarbon Radicals At 4°k in Raregas Matricas / By Keith Ingram Dismuke
Dismuke, Keith Ingram
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This was attributed to a CEC-H bending mode, v_. Upon deutera- tion, a similar transition was observed with a vibrational spacing of 836 cm due to the C=C-D bending mode, v . An attempt was made to produce C.H trapped in neon at 4 K in hopes of sharpening the vibrational structure of the bands observed in argon. Due to the difficulty of trapping H atoms from the photolysis in neon, the observed spectrum was weak and individual bands were broad. However, two progressions were observed due to the... C=C and C-C stretching modes. Table XVII lists the transitions and frequency differences observed for C H in 4 153 Table XVII Vibrational assignments for the 3000 8 transitions of C.H:Ne at 4°K. 4 A (8) v(cm _1 ) AG 2963 33740 804 2894 34544 2028 2795 35768 771 2736 36539 2014 2646 37782 712 2597 38494 a Vibrational Assignments V 2 V 4 1 1 1 1 2 2 1 v 2 and v A are the vibrational quantum numbers for the C=C and C-C stretching modes, respectively. 154 Infrared Spectra New transitions which, occur in the infrared region when C H and C.D are prepared in the matrix are shown in Figure 25.
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