Elementary Chemistry

Cover Elementary Chemistry
Elementary Chemistry
C E Charles Elijah Linebarger
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Nitrogen pentoxid is prepared by the action of phosphorus pentoxid on very concentrated nitric acid at low temperatures. It is a white, crystalline substance melting at 30 with partial decomposition, while at 47 it decom- poses rapidly into oxygen and nitrogen dioxid.
172. Nitrogen Dioxid and Tetroxid (Peroxid). Nitrogen dioxid and tetroxid may be prepared (/) by mixing two volumes of nitric oxid with one of oxy- gen, and (2) by heating lead or manganous nitrate.
At low temperatures nitrogen pe
...roxid is a color- less solid, melting at -12 into a light yellow liquid which, as the temperature rises, assumes a deeper and deeper tint. At 25 the liquid boils, giving off a vapor of a reddish-brown color. The color of this vapor deepens as the temperature continues to rise, until at 50 it is so brown as to be almost opaque. When the temperature is lowered, the reverse changes occur; we have to do with a rever- sible reaction.
i6o Elementary Clicmistry NITRIC ACID 173. Occurrence. Free nitric acid is not met with in nature except in minute amounts in the air after thunder storms.


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