Elements of Qualitative And Quantitative Chemical Analysis

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NH,OH ppts. zinc hydroxide, Zn(OH) 2 , fiocculent, white, soluble in excess of precipitant, as (NHJ.jZnOa, re-pptd. on boiling as Zn(OH) 2 .
BaCOj does not ppt. this hydroxide, except from solutions of the sulphate.
§ 9i b.] Elements of Chemical Analysis. 99 54. Filtrate;. To a portion add acetic acid and then H 2 S. A white ppt., soluble in HC1 shows Zn.
55. Evaporate another/ small portion carefully to dryness in the platinum cup, and fuse the residue with a mixture of equal parts of Na 2 CO
...s and KNO s . A bluish-green color in, the fused mass shows Mn.
56. a. Phosphate was present and Zn or Mn are absent; add the remainder of filtrate 53 to filtrate 47 for the Ca group, remembering that Ba has already been .tested for be- fore the addition of BaC0 3 in 53 t».
t». Phosphate was present, and Zn and Mn also ; add to the remainder of filtrate 53 NH 4 C1, NH.OH and (NH 4 ) 2 S, warm and filter ; dispose of this filtrate as in a above.
ioo Elements of Chemical Analysis. [§ 92.
92. Notes on the.


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